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Advanced materials (Deerfield Beach, Fla.)

n-Doping of organic electronic materials using air-stable organometallics.


PMID 22057596

Abstract

Air-stable dimers of sandwich compounds including rhodocene and (pentamethylcyclopentadienyl)(arene)ruthenium and iron derivatives can be used for n-doping electron-transport materials with electron affinities as small as 2.8 eV. A p-i-n homojunction diode based on copper phthalocyanine and using rhodocene dimer as n-dopant shows a rectification ratio of greater than 10(6) at 4 V.

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795615
Pentamethylcyclopentadienyl cyclopentadienyl rhodium dimer
C30H40Rh2