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Organic & biomolecular chemistry

Palladium-catalyzed S-benzylation of unprotected mercaptobenzoic acid with benzyl alcohols in water.


PMID 22402746

Abstract

Palladium-catalyzed S-benzylation of unprotected mercaptobenzoic acids with benzyl alcohols gave only S-benzylated mercaptobenzoic acids in good yields. Water may play an important role for the smooth generation of the (η(3)-benzyl)palladium species by activation of the hydroxyl group of the benzyl alcohol.

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