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Macromolecular rapid communications

Synthesis of polyethylene containing allene groups: a simple and efficient route to functional polyethylene.


PMID 22411771

Abstract

Allene groups are first employed as the reactive moiety in the simple and efficient synthesis of well-defined functional polyethylene. By copolymerization of ethylene with allene group substituted norbornene, the allene group is successfully introduced into the polyethylene with a high content. The retained allene groups are demonstrated to be highly reactive in following photoinduced functionalized reactions and can be efficiently converted into the functional groups without the multi-step, time consuming processes that have generally been required in previous reports, providing the side group-functionalized polyethylene with a wide range of functional group content.

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294985
Allene, ≥95%
C3H4