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The Journal of organic chemistry

Heteropolyacid-catalyzed direct deoxygenation of propargyl and allyl alcohols.


PMID 22849794

Abstract

The combination of H(3)[PW(12)O(40)]·nH(2)O (1 mol %) and Et(3)SiH led to the direct catalytic deoxygenation of propargyl alcohols, in which proper solvent selection Cl(CH(2))(2)Cl vs CF(3)CH(2)OH was the key to obtaining better product yields. Under similar conditions, the deoxygenation of allyl alcohols proceeded to give thermodynamically stable alkenes with migration of the double bonds in good yields.

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P50803
Propargyl alcohol, 99%
C3H4O