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Carbohydrate research

The synthesis of 2-deoxy-α-D-glycosides from D-glycals catalyzed by TMSI and PPh3.


PMID 22854184

Abstract

2-Deoxyglycosides were synthesized in high α-selectivity by the direct addition of alcohols to D-glucal and D-galactal catalyzed by TMSI and PPh(3). The acid labile isopropylidene group is tolerated under this condition.

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464058
D-Glucal, 96%
C6H10O4