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Chemical communications (Cambridge, England)

Chiral Brønsted acid catalyzed enantioselective allenylation of aldehydes.


PMID 22872133

Abstract

A versatile and highly enantioselective chiral Brønsted acid-catalyzed allenylation of aldehydes with propargyl borolane is reported. The reaction is shown to be practical and quite general with a broad substrate scope covering aryl, heteroaryl, α,β-unsaturated, and aliphatic aldehydes.

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