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Chemical communications (Cambridge, England)

A carbazole-containing porphyrinoid: synthesis and oxidation to the porphyrin-state.


PMID 22908132

Abstract

Carbazole-containing porphyrinoid was synthesised for the first time via Suzuki-Miyaura cross-coupling reaction. Oxidation with MnO(2) yielded its porphyrin-state featuring macrocyclic aromaticity in exchange for the loss of the resonance energies of the benzene rings.