EMAIL THIS PAGE TO A FRIEND

Organic letters

Azobisisobutyronitrile initiated aerobic oxidative transformation of amines: coupling of primary amines and cyanation of tertiary amines.


PMID 23106189

Abstract

In the presence of a catalytic amount of radical initiator AIBN, primary amines are oxidatively coupled to imines and tertiary amines are cyanated to α-aminonitriles. These "metal-free" aerobic oxidative coupling reactions may find applications in a wide range of "green" oxidation chemistry.

Related Materials

Product #

Image

Description

Molecular Formula

Add to Cart

768375
Azobisisobutyronitrile, 12 wt. % in acetone
C8H12N4