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Chemistry & biodiversity

Synthesis of highly functionalized fluorinated cispentacin derivatives.


PMID 23161635

Abstract

Fluorinated highly functionalized cispentacin derivatives were synthetised starting from an unsaturated bicyclic β-lactam through C=C bond functionalization via the dipolar cycloaddition of a nitrile oxide, isoxazoline opening, and fluorination by OH/F exchange.

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