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Chemical communications (Cambridge, England)

Copper-catalyzed nucleophilic trifluoromethylation of propargylic halides.


PMID 23884450

Abstract

Reactions of propargylic halides with trifluoromethyltrimethylsilane in the presence of a catalytic amount of copper(I) thiophene-2-carboxylate (CuTC) have been found to give the corresponding trifluoromethylated products in good to high yields with a high selectivity.

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