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The Journal of organic chemistry

Carbon-sulfur bond formation catalyzed by [Pd(IPr*(OMe))(cin)Cl] (cin = cinnamyl).


PMID 23937148

Abstract

The newly prepared complex [Pd(IPr*(OMe))(cin)(Cl)] provides high catalytic activity for carbon-sulfur cross-coupling reactions. Nonactivated and deactivated aryl halides were successfully coupled with a large variety of aryl- and alkylthiols using this well-defined palladium N-heterocyclic carbene (NHC) complex.

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