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The Journal of organic chemistry

Cu-NHC-TEMPO catalyzed aerobic oxidation of primary alcohols to aldehydes.


PMID 23944937

Abstract

Imidazolium salts bearing TEMPO groups react with commercially available copper powder affording Cu-NHC complexes. The in situ generated Cu-NHC-TEMPO complexes are quite efficient catalysts for aerobic oxidation of primary alcohols into aldehydes. The catalyst is easily available, and various primary alcohols were selectively converted to aldehydes in excellent yields.

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426369
TEMPO, purified by sublimation, 99%
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