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Journal of the American Chemical Society

Palladium(III)-catalyzed fluorination of arylboronic acid derivatives.


PMID 24040932

Abstract

A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd(III) intermediate that has been isolated and characterized.

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