EMAIL THIS PAGE TO A FRIEND

Organic letters

A modular, air-stable nickel precatalyst.


PMID 25886092

Abstract

The synthesis and catalytic activity of [(TMEDA)Ni(o-tolyl)Cl], an air-stable, crystalline solid, is described. This complex is an effective precatalyst in a variety of nickel-catalyzed transformations. The lability of TMEDA allows a wide variety of ligands to be used, including mono- and bidentate phosphines, diimines, and N-heterocyclic carbenes. Preliminary mechanistic studies are also reported, which suggest that [(TMEDA)Ni(o-tolyl)Cl] can activate by either a Ni-B or Ni-Ni transmetalation event, depending on the reaction conditions.

Related Materials

Product #

Image

Description

Molecular Formula

Add to Cart

804398
[(TMEDA)Ni(o-tolyl)Cl], 95%
C13H23ClN2Ni