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Chemistry (Weinheim an der Bergstrasse, Germany)

Reactions of Trimethylaluminium: Modelling the Chemical Degradation of Synthetic Lubricants.


PMID 27792841

Abstract

In investigating and seeking to mimic the reactivity of trimethylaluminium (TMA) with synthetic, ester-based lubricating oils, the reaction of methyl propionate 1 was explored with 1, 2 and 3 equivalents of the organoaluminium reagent. Spectroscopic analysis points to the formation of the adduct 1(TMA) accompanied only by the low level 1:1 production of Me

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