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International journal of peptide and protein research

Cleavage of aspartyl beta-phenacyl esters by selenophenol under neutral conditions.


PMID 7118418

Abstract

Neutral selenophenol in DMF accomplished the removal of the beta-phenacyl protecting group of aspartic acid in solution, on the peptide Boc-Asp (beta-OPac)- Phe amide and on the resin peptide Boc-Trp(Nin-For)-Met-Asp (beta-OPac)-P (CCK 30-33) without alpha, beta-rearrangement.

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375152
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C6H6Se