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151858 Aldrich

Chloroform-d

"100%", 99.96 atom % D

Synonym: Deuterochloroform

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Properties

Related Categories Alphabetical Listings, C, Chloroform, Chloroform-d, NMR Solvents,
InChI Key   HEDRZPFGACZZDS-MICDWDOJSA-N
isotopic purity   99.96 atom % D
assay   ≥99% (CP)
refractive index   n20/D 1.444(lit.)
bp   60.9 °C(lit.)
mp   −64 °C(lit.)
density   1.500 g/mL at 25 °C(lit.)
mass shift   M+1

Description

Packaging

10×0.25, 10×0.5, 10×0.75, 10×1 mL in ampule

10, 50 g in glass bottle

General description

Chloroform-d (Deuterochloroform, CDCl3), deuterated chloroform, is a 100% isotopically enriched NMR (Nuclear Magnetic Resonance) solvent. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. Quantitaive infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the in the ν1 and ν2 bands of CHCl3 and CDCl3.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
RIDADR 
UN 1888 6.1 / PGIII
WGK Germany 
3

LC-MS Grade Solvents and Reagents
Protocols & Articles

Articles

Pressure-Temperature Calculator for Solvents

*Calculations provide estimated results based on Antoine's Coefficients and their associated temperature range values. Antoine's Coefficients were obtained from the National Institute of Standards an...

Related Content

Pressure-Temperature Nomograph Interactive Tool

The Pressure-Temperature Nomograph tool is an application of the Clausius-Clapeyron Equation, which assumes the heat of vaporization is a constant over a pressure range. Antoine´s Equation gets aroun...
Keywords: Evaporation, Vaporization

Properties of Solvents Table

a. Gant, R., LC/GC 10 (7), 515 (1992) 1. At 20 °C 2. At 20 °C +/- 5 °C relative to water at 4 °C 3. At 10 mmHg pressure 4. At l=589.32 nm
Keywords: Gas chromatography, High performance liquid chromatography

Peer-Reviewed Papers
15

References

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