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167398 Aldrich

tert-Butyl carbamate

98%

Synonym: Boc-amide

  • CAS Number 4248-19-5

  • Linear Formula NH2COOC(CH3)3

  • Molecular Weight 117.15

  •  Beilstein Registry Number 1744500

  •  EC Number 224-209-3

  •  MDL number MFCD00007962

  •  PubChem Substance ID 24850207

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Properties

Related Categories Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Protected Amines More...
InChI Key   LFKDJXLFVYVEFG-UHFFFAOYSA-N
assay   98%
mp   105-108 °C (lit.)

Description

Packaging

1, 5, 25, 100 g in glass bottle

Application

tert-Butyl carbamate was used in palladium-catalyzed synthesis of N-Boc-protected anilines. It was used in the synthesis of tetrasubstituted pyrroles, functionalized with ester or ketone groups at C-3 position.

General description

Palladium-catalyzed cross-coupling reaction of tert-butyl carbamate with various aryl(Het) halides with Cs2CO3 as base in 1,4-dioxane (solvent) has been investigated.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

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Protocols & Articles
Peer-Reviewed Papers
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References

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