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183695 Sigma-Aldrich

2′-Bromoacetophenone

99%

Synonym: 1-Acetyl-2-bromobenzene

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Properties

Related Categories Building Blocks, C7 to C8, Carbonyl Compounds, Chemical Synthesis, Ketones,
Quality Level   100
assay   99%
refractive index   n20/D 1.568 (lit.)
density   1.476 g/mL at 25 °C (lit.)
SMILES string   CC(=O)c1ccccc1Br
InChI   1S/C8H7BrO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3
InChI key   PIMNFNXBTGPCIL-UHFFFAOYSA-N

Description

General description

2′-Bromoacetophenone (2-Bromoacetophenone) undergoes enantioselective addition reaction with phenylacetylene catalyzed by chiral camphorsulfonamide. It reacts with aliphatic primary amines in the presence of palladium catalyst to afford 3-methyleneisoindolin-1-ones.

Application

2′-Bromoacetophenone (2-Bromoacetophenone) was used in the synthesis of novel series of non-condensed 5,5-bicycles.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
230.0 °F - closed cup
Flash Point(C) 
110 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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