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187186 Aldrich

Cinnamyl chloride

95%

Synonym: (3-Chloropropenyl)benzene

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Properties

Related Categories Acyclic, Alkenes, Building Blocks, Chemical Synthesis, Organic Building Blocks More...
InChI Key   IWTYTFSSTWXZFU-QPJJXVBHSA-N
assay   95%
refractive index   n20/D 1.584(lit.)
bp   108 °C/12 mmHg(lit.)
mp   −19 °C (lit.)
density   1.096 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Packaging

5, 100 g in glass bottle

Application

Cinnamyl chloride was used in the enantioselective total synthesis of helioporins C and E, bioactive marine diterpenes.

General description

Cinnamyl chloride reacts regioselectively with aryl and alkenylgold(I) phosphanes in the presence of palladium catalyst in THF to afford the α-substitution product†.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1760 8 / PGII
WGK Germany 
3
RTECS 
CZ0919905
Flash Point(F) 
174.2 °F
Flash Point(C) 
79 °C

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Peer-Reviewed Papers
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References

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