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209384 Sigma-Aldrich

3-Methoxybenzyl chloride

97%

Synonym: 3-(Chloromethyl)anisole

  • CAS Number 824-98-6

  • Linear Formula CH3OC6H4CH2Cl

  • Molecular Weight 156.61

  •  Beilstein/REAXYS Number 636684

  •  MDL number MFCD00000907

  •  PubChem Substance ID 24852566

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C8, Chemical Synthesis, Ethers, Organic Building Blocks,
assay   97%
contains   potassium carbonate as stabilizer
refractive index   n20/D 1.544 (lit.)
bp   124 °C/13 mmHg (lit.)
density   1.078 g/mL at 25 °C (lit.)
  1.078 g/mL
storage temp.   2-8°C
SMILES string   COc1cccc(CCl)c1
InChI   1S/C8H9ClO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3
InChI key   VGISFWWEOGVMED-UHFFFAOYSA-N

Description

Application

3-Methoxybenzyl chloride was used to alkylate 8-benzyloxy-2(1H)-quinolinone in the presence of DMF and NaH. It was also used in the synthesis of diarylmethanes via in situ organozinc-mediated, palladium-catalyzed cross-coupling between benzyl and aryl halide.

Packaging

5, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3265 8 / PGII
WGK Germany 
WGK 1
Flash Point(F) 
213.8 °F - closed cup
Flash Point(C) 
101 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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