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219584 Sigma-Aldrich

2,6-Di-tert-butylpyridine

≥97%

  • CAS Number 585-48-8

  • Empirical Formula (Hill Notation) C13H21N

  • Molecular Weight 191.31

  •  Beilstein/REAXYS Number 125886

  •  EC Number 209-557-6

  •  MDL number MFCD00006306

  •  PubChem Substance ID 24853137

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C13 to C15, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines More...
assay   ≥97%
refractive index   n20/D 1.473 (lit.)
bp   100-101 °C/23 mmHg (lit.)
density   0.852 g/mL at 25 °C (lit.)
storage temp.   2-8°C
SMILES string   CC(C)(C)c1cccc(n1)C(C)(C)C
InChI   1S/C13H21N/c1-12(2,3)10-8-7-9-11(14-10)13(4,5)6/h7-9H,1-6H3
InChI key   UWKQJZCTQGMHKD-UHFFFAOYSA-N

Description

General description

Reactivity of 2,6-di-tert-butylpyridine with iron(III) tetraphenylporphyrin pi-cation radical has been examined by proton NMR spectroscopy. Reaction of 2,6-di-tert-butylpyridine with methyl iodide and methyl fluorosulfonate under high pressure has been reported.

Application

2,6-Di-tert-butylpyridine was used as proton trapping agent to investigate the living polymerization of isobutylene. It was also used with cerric ammonium nitrate in the α-enolation of aldehydes leading to 1,4-dicarbonyl systems.

Packaging

1, 5, 25 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
WGK Germany 
3
Flash Point(F) 
159.8 °F
Flash Point(C) 
71 °C

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Protocols & Articles
Peer-Reviewed Papers
15

References

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