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226084 Aldrich

(Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate

97%

Synonym: BOP Reagent, BOP, Castros reagent

  • CAS Number 56602-33-6

  • Empirical Formula (Hill Notation) C12H22F6N6OP2

  • Molecular Weight 442.28

  •  Beilstein Registry Number 4287025

  •  EC Number 260-279-1

  •  MDL number MFCD00011948

  •  PubChem Substance ID 24853542

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Properties

Related Categories Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling,
InChI Key   MGEVGECQZUIPSV-UHFFFAOYSA-N
assay   97%
mp   >130 °C (dec.)(lit.)
storage temp.   2-8°C

Description

Packaging

1, 5 g in glass bottle

Application

Reagent for:
Peptide coupling
Synthesis of esters
Esterification of carboxylic acids
Plasmid CAN-encapsulating liposomes
Synthesis of magnolamide for antioxidative activity

Catalyst for preparation of 9-acridinecaroboxamide derivative

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Risk of explosion if heated under confinement.
Personal Protective Equipment 
RIDADR 
UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
WGK Germany 
3

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Protocols & Articles

Articles

Phosphonium Salts

Phosphonium salts are powerful and easy-to-use peptide coupling reagents that allow in situ generation of active esters. After the recognition of chlorotris(dimethylamino)phosphonium as the activatin...
Matthias Junkers
ChemFiles 2007, 7.2, 8.
Keywords: Peptide synthesis

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COMU – Safer and More Efficient Peptide Coupling Reagent

Peptide synthesis relies heavily on efficient and reliable coupling reagents. A low tendency for racemization is a key requirement. This is especially true for solid phase peptide synthesis—quantitat...
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Indoles, Purines, and Their Isosteres

Substituted indoles and purines have frequently been referred to as “privileged structures” since they are capable of binding to multiple receptors with high affinity, and thus have applications acro...
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Peer-Reviewed Papers
15

References

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