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236454 Sigma-Aldrich

Methyl 2-aminobenzoate

ReagentPlus®, ≥99%

Synonym: Methyl anthranilate

  • CAS Number 134-20-3

  • Linear Formula 2-(H2N)C6H4CO2CH3

  • Molecular Weight 151.16

  •  Beilstein/REAXYS Number 606965

  •  EC Number 205-132-4

  •  MDL number MFCD00007710

  •  PubChem Substance ID 24854171

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C8 to C9, Carbonyl Compounds, Cell Biology, Chemical Synthesis,
grade   ReagentPlus®
vapor pressure   1 mmHg ( 20 °C)
assay   ≥99%
autoignition temp.   986 °F
refractive index   n20/D 1.582 (lit.)
bp   256 °C (lit.)
mp   24 °C (lit.)
solubility   alcohol: freely soluble(lit.)
  diethyl ether: freely soluble(lit.)
  water: slightly soluble(lit.)
density   1.168 g/mL at 25 °C (lit.)
SMILES string   COC(=O)c1ccccc1N
InChI   1S/C8H9NO2/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5H,9H2,1H3
InChI key   VAMXMNNIEUEQDV-UHFFFAOYSA-N

Description

General description

Methyl 2-aminobenzoate reacts with 2,4-bis(4-methoxyphenyl)-1,3,2,4-dithiadiphosphetane-2,4-disulphide at 140°C to yield 1,2-dihydro-2-(p-methoxyphenyl)-4H-3,1,2-benzothiazaphosphorin-4-thione-2-sulfide and dimethyl-4-methoxyphenylphosphonotrithioate.

Application

Methyl 2-aminobenzoate has been used in the synthesis of novel 4-chloro-2-mercaptobenzenesulfonamide derivatives.

Packaging

50 g in glass bottle

Legal Information

ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
1
RTECS 
CB3325000
Flash Point(F) 
253.4 °F
Flash Point(C) 
123 °C

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Meet Synthia - Retrosynthesis Sofware
Protocols & Articles
Peer-Reviewed Papers
15

References

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