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241814 Sigma-Aldrich

Lithium tri-tert-butoxyaluminum hydride solution

1.0 M in THF

  • CAS Number 17476-04-9

  • Linear Formula LiAlH[OC(CH3)3]3

  • Molecular Weight 254.27

  •  Beilstein/REAXYS Number 5796791

  •  MDL number MFCD00011532

  •  PubChem Substance ID 24854332

  •  NACRES NA.22

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Properties

Related Categories Aluminum Hydrides, Chemical Synthesis, Reduction, Synthetic Reagents
Quality Level   100
concentration   1.0 M in THF
density   0.904 g/mL at 25 °C
SMILES string   [Li+].CC(C)(C)O[AlH-](OC(C)(C)C)OC(C)(C)C
InChI   1S/3C4H9O.Al.Li.H/c3*1-4(2,3)5;;;/h3*1-3H3;;;/q3*-1;+2;+1;
InChI key   BYBIDFZFKATBFH-UHFFFAOYSA-N

Description

General description

Lithium tri-tert-butoxyaluminum hydride is a mild reducing agent mainly used for the selective reduction of ketones.

Application

• Reducing agent

Packaging

100, 800 mL in Sure/Seal™

Safety & Documentation

Safety Information

Signal word 
Danger
Supplemental Hazard Statements 
EUH014 - EUH018 - EUH019
RIDADR 
UN 3399A 4.3(3) / PGI
WGK Germany 
WGK 1
Flash Point(F) 
1.4 °F - closed cup
Flash Point(C) 
-17 °C - closed cup

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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