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277681 Sigma-Aldrich

3-Methyl-3-oxetanemethanol

98%

Synonym: 3-Hydroxymethyl-3-methyl-oxetane

  • CAS Number 3143-02-0

  • Empirical Formula (Hill Notation) C5H10O2

  • Molecular Weight 102.13

  •  Beilstein/REAXYS Number 102773

  •  MDL number MFCD00010273

  •  PubChem Substance ID 24856780

  •  NACRES NA.22

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Properties

Related Categories Alcohols, Asymmetric Synthesis, Building Blocks, C2 to C6, Chemical Synthesis,
InChI Key   NLQMSBJFLQPLIJ-UHFFFAOYSA-N
assay   98%
refractive index   n20/D 1.446 (lit.)
bp   80 °C/40 mmHg (lit.)
density   1.024 g/mL at 25 °C (lit.)
storage temp.   2-8°C

Description

Application

3-Methyl-3-oxetanemethanol has been used in the preparation of:
• star-shaped copolymer consisting of a hyperbranched poly(3-methyl-3-oxetanemethanol) core and polytetrahydrofuran arms
• pyridyl disulfide-functionalized cyclic carbonate monomer, required for the synthesis of of functional poly(ε-caprolactone) containing pendant pyridyl disulphide groups
• δ-lactams

Packaging

10, 50 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
206.6 °F
Flash Point(C) 
97 °C

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Oxetanes

Oxetanes are the closest homologs to epoxides, but historically have received far less attention than their three-membered ringed brethren. However, oxetanes have received increasing exposure as attr...
Mark Redlich
Chemfiles Volume 10 Article 4
Keywords: Antibiotics, Building blocks, Drug discovery, Medicinal chemistry

Peer-Reviewed Papers
15

References

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