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283207 Sigma-Aldrich

Magnesium bis(monoperoxyphthalate) hexahydrate

Green Alternative

80%, technical grade

Synonym: MMPP

  • Linear Formula (HO2CC6H4CO3)2Mg·6H2O

  • Molecular Weight 494.64

  •  EC Number 279-013-0

  •  MDL number MFCD00149614

  •  PubChem Substance ID 24857092

  •  NACRES NA.22

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Properties

Related Categories 12 Principles Aligned Products, Chemical Synthesis, Greener Alternative Products, Greener Synthetic Reagents, Oxidizing Agents,
Quality Level   200
grade   technical grade
assay   80%
greener alternative product characteristics   Designing Safer Chemicals
Learn more about the Principles of Green Chemistry.
mp   93 °C (dec.) (lit.)
greener alternative category   Aligned
SMILES string   O.O.O.O.O.O.OOC(=O)c1ccccc1C(=O)O[Mg]OC(=O)c2ccccc2C(=O)OO
InChI   1S/2C8H6O5.Mg.6H2O/c2*9-7(10)5-3-1-2-4-6(5)8(11)13-12;;;;;;;/h2*1-4,12H,(H,9,10);;6*1H2/q;;+2;;;;;;/p-2
InChI key   WWOYCMCZTZTIGU-UHFFFAOYSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product MMPP is an alternative to widely used oxidant MCPBA as it is cheap, stable in the solid state, safer in handling and easier to use and thus aligns with the principle "Designing Safer Chemicals". For more information see the below articles.
Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones.
Magnesium Bis(monoperoxyphthalate) Hexahydrate (MMPP).
Highly efficient epoxidation of unsaturated steroids using magnesium bis(monoperoxyphthalate) hexahydrate.

Application

A safer, greener oxidizing reagent that is a suitable replacement for peroxycarboxylic acids and is capable of effecting many types of oxidation reactions.

Oxidation Reactions Using Magnesium Monoperphthalate: A Comparison with m-Chloroperoxybenzoic Acid

Reagent for:
• Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
• Oxidation rections under mild conditions
• Epoxidation of unsaturated steroids
• Synthesis of ring-B oxygenated steroids as anticancer agents

Packaging

100 g in poly bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 2
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles

Articles

Oxidizing and Reducing Agents

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis, and are some of the organic chemist’s most powerful tools for creating novel products. ...
ChemFiles Volume 1 Article 3
Keywords: Organic synthesis, Oxidations, Reductions

Peer-Reviewed Papers
15

References

Related Products

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