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29590 Aldrich

(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate

≥99.0% (C)

Synonym: (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6, Crabtree’s catalyst, Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex, [Ir(cod)(PCy3)(py)]PF6, [Ir(cod)(PCy3)(py)]PF6

  • CAS Number 64536-78-3

  • Empirical Formula (Hill Notation) C31H50F6IrNP2

  • Molecular Weight 804.89

  •  MDL number MFCD00075097

  •  PubChem Substance ID 57648382

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Iridium Catalysts More...
InChI Key   UJXHUUQZACSUOG-KJWGIZLLSA-N
assay   ≥99.0% (C)
mp   175 °C (dec.) (lit.)

Description

Other Notes

Catalyst for the homogeneous hydrogenation of olefins

Packaging

250 mg in glass bottle

Bottomless glass bottle. Contents are inside inserted fused cone.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis


Screeing simplified
Protocols & Articles

Articles

Robert Crabtree Group – Professor Product Portal

From our library of Articles, Sigma-Aldrich presents Robert Crabtree Group – Professor Product Portal
Keywords: Asymmetric synthesis, Hydrogenations

Peer-Reviewed Papers
15

References

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