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324175 Sigma-Aldrich

Lithium 2-thienylcyanocuprate solution

0.25 M in THF

  • CAS Number 112426-02-5

  • Empirical Formula (Hill Notation) C5H3CuLiNS

  • Molecular Weight 179.64

  •  MDL number MFCD00013443

  •  PubChem Substance ID 24859429

  •  NACRES NA.22

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Properties

Related Categories Chemical Synthesis, Organocopper, Organometallic Reagents More...
Quality Level   100
concentration   0.25 M in THF
density   0.895 g/mL at 25 °C
SMILES string   [Li]N=C=[Cu]c1cccs1
InChI   1S/C4H3S.CN.Cu.Li/c1-2-4-5-3-1;1-2;;/h1-3H;;;/q;-1;;+1
InChI key   BDZYNOMLDVYLHW-UHFFFAOYSA-N

Description

General description

Learn More at the Professor and Product Portal of Professor Bruce Lipshutz.

Packaging

100, 800 mL in Sure/Seal™

Application

Useful reagent for the preparation of higher-order cuprates.

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Target organs 
Respiratory system
Supplemental Hazard Statements 
EUH019
RIDADR 
UN 2056 3 / PGII
WGK Germany 
WGK 3
Flash Point(F) 
1.4 °F - closed cup
Flash Point(C) 
-17 °C - closed cup

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Lipshutz Group – Products available at Aldrich from the Lipshutz Laboratory

From our library of Articles, Sigma-Aldrich presents Lipshutz Group – Products available at Aldrich from the Lipshutz Laboratory
Keywords: Addition reactions, Catalysis, Cross couplings, Environmental, Green chemistry, Ligands, Metathesis, Nucleophilic aromatic substitution, Olefin metathesis, Organic synthesis, Solvents, Substitutions

Peer-Reviewed Papers
15

References

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