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324833 Sigma-Aldrich

2-Bromo-5-nitropyridine

99%

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Properties

Related Categories Building Blocks, C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks,
Quality Level   100
assay   99%
bp   145-147 °C/10 mmHg (lit.)
mp   139-141 °C (lit.)
SMILES string   [O-][N+](=O)c1ccc(Br)nc1
InChI   1S/C5H3BrN2O2/c6-5-2-1-4(3-7-5)8(9)10/h1-3H
InChI key   HUUFTVUBFFESEN-UHFFFAOYSA-N

Description

Application

2-Bromo-5-nitropyridine was used in preparation of boc-protected (piperazin-1-ylmethyl)biaryls via microwave-mediated Suzuki-Miyaura coupling with (boc-piperazin-1-ylmethyl)phenylboronic acid pinacol esters. It was also used in the synthesis of 2-pyridyl analogs.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS06  GHS06
Signal word 
Danger
Hazard statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
UN 2811 6.1 / PGIII
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles
Peer-Reviewed Papers
15

References

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