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325252 Sigma-Aldrich

Titanium diisopropoxide bis(acetylacetonate)

75 wt. % in isopropanol

Synonym: Diisopropoxytitanium bis(acetylacetonate) solution, TYZOR® AA organic titanate, Ti(acac)2OiPr2

  • CAS Number 17927-72-9

  • Linear Formula [(CH3)2CHO]2Ti(C5H7O2)2

  • Molecular Weight 364.26

  •  MDL number MFCD00000031

  •  PubChem Substance ID 24859496

  •  NACRES NA.23

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Properties

Related Categories Alternative Energy, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics,
Quality Level   200
form   solution
concentration   75 wt. % in isopropanol
refractive index   n20/D 1.4935
density   0.995 g/mL at 25 °C
SMILES string   CC(C)O[Ti](OC(C)C)(O\C(C)=C\C(C)=O)O\C(C)=C\C(C)=O
InChI   1S/2C5H8O2.2C3H7O.Ti/c2*1-4(6)3-5(2)7;2*1-3(2)4;/h2*3,6H,1-2H3;2*3H,1-2H3;/q;;2*-1;+4/p-2/b2*4-3+;;;
InChI key   OVSGBKZKXUMMHS-VVDZMTNVSA-L

Description

Application

Titanium diisopropoxide bis (acetylacetonate) (TAA) may be used as a precursor to develop self assembled macroporous titania particles by evaporation. Commercial titanium(IV) bis(acetylacetonate) diisopropoxide was used to synthesize titanium acetylacetonate xerogels by drying, which could be further used to prepare titania films. TAA may be used as a hole blocking layer to fabricate solar cells.

Packaging

100, 500 mL in glass bottle

Legal Information

TYZOR is a registered trademark of E. I. du Pont de Nemours and Company

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Target organs 
Central nervous system
RIDADR 
UN1219 - class 3 - PG 2 - Isopropanol, solution
WGK Germany 
WGK 3
Flash Point(F) 
53.6 °F - closed cup
Flash Point(C) 
12 °C - closed cup
Protocols & Articles

Articles

A Review of Mesoporous TiO2 Thin Films

Jinshu Wang*, Junshu Wu, Hongyi Li The Key Lab of Advanced Functional Materials, Ministry of Education China, School of Materials Science and Engineering, Beijing University of Technology, Beijing 10...
Keywords: Adsorption, Building blocks, Catalysis, Ceramics, Condensations, Cosmetics, Degradations, Diffraction, Eliminations, Evaporation, Materials Science, Oxidations, Polymerization reactions, Semiconductor, Separation, Sol-gel

Few Monolayer Atomic Layer Deposition (ALD) on Surfaces and Interfaces for Energy Applications

Department of Mechanical Engineering and Materials Science, One Brookings Drive, Washington University in St. Louis, St. Louis, MO 63130 *Email: parag.banerjee@wustl.edu
Keywords: Atomic layer deposition, Catalysis, Chemical reactions, Degradations, Dehydrogenation, Deposition, Hydrogenations, Ion Exchange, Ligands, Magnetic resonance spectroscopy, Materials Science, Nanomaterials, Oxidations, Photovoltaics, Precipitation, Recombination, Reductions, Renewable energy, Separation, Solar cells, Thin film deposition

Mesoporous Titanium Dioxide Thin Films

Titanium dioxide (TiO2) is an important n-type semiconducting material that shows interesting characteristics such as photoswitchable surface wettability, high photocatalytic activity, bistable elect...
Jinshu Wang, Junshu Wu, Hongyi Li
Material Matters, Volume 7, Number 2, 2–6
Keywords: Adsorption, Building blocks, Catalysis, Ceramics, Condensations, Cosmetics, Degradations, Diffraction, Eliminations, Evaporation, Materials Science, Oxidations, Polymerization reactions, Semiconductor, Separation, Sol-gel

Nanowire Synthesis: From Top-Down to Bottom-Up

David J. Hill, James F. Cahoon* Department of Chemistry, University of North Carolina at Chapel Hill, USA *Email: jfcahoon@unc.edu
David J. Hill, James F. Cahoon*
Material Matters, 2017, 12.1
Keywords: Absorption, Catalysis, Chemical vapor deposition, Deposition, Electronics, Melting, Microelectronics, Nanomaterials, Redox Reactions, Reductions, Semiconductor

Novel Inks for Direct-Write Assembly of 3-D Periodic Structures

New methods for materials fabrication at the micro- and nanoscale will drive scientific and technological advances in areas of materials science, chemistry, physics, and biology. The broad diversity ...
Prof. Jennifer A. Lewis
Material Matters 2008, 3.1, 4.
Keywords: Applications, Biomaterials, Capabilities, Coagulants, Coagulation, Deposition, Environmental, Materials Science, Methods, Photographs, Reductions, Semiconductor, Size-exclusion chromatography, Sol-gel, Support, Type

Surface-enhanced Solar Energy Conversion Systems Using Gold and Silver Nanoparticles

Sustainable, environment-friendly, and clean energy sources with sufficiently high production efficiency for practical application are highly desirable to meet the energy challenge of the 21st centur...
Shanlin Pan and Arunava Gupta
Material Matters, 2012 v7, n4
Keywords: Absorption, Catalysis, Chemical vapor deposition, Degradations, Deposition, Diffusion, Electronics, Organic electronics, Photovoltaics, Recombination, Renewable energy, Semiconductor, Separation, Solar cells

Peer-Reviewed Papers
15

References

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