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  • 339830 - 2-[(Acetoxymethyl)allyl]trimethylsilane

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339830 Sigma-Aldrich

2-[(Acetoxymethyl)allyl]trimethylsilane

99%

Synonym: 2-(Trimethylsilylmethyl)-2-propen-1-yl acetate, 2-(Trimethylsilylmethyl)allyl acetate, 2-Acetoxymethyl-3-(trimethylsilyl)propene

  • CAS Number 72047-94-0

  • Linear Formula CH3CO2CH2C(=CH2)CH2Si(CH3)3

  • Molecular Weight 186.32

  •  Beilstein/REAXYS Number 1933657

  •  MDL number MFCD00075170

  •  PubChem Substance ID 24860688

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C8 to C9, Carbonyl Compounds, Chemical Synthesis, Esters,
Quality Level   100
assay   99%
refractive index   n20/D 1.440 (lit.)
bp   95 °C/7 mmHg (lit.)
density   0.877 g/mL at 25 °C (lit.)
SMILES string   CC(=O)OCC(=C)C[Si](C)(C)C
InChI   1S/C9H18O2Si/c1-8(6-11-9(2)10)7-12(3,4)5/h1,6-7H2,2-5H3
InChI key   IKQWABMHZKGCLX-UHFFFAOYSA-N

Description

Application

2-[(Acetoxymethyl)allyl]trimethylsilane was used in the cyclopentane synthesis via Pd(0)-catalyzed reactions with 2π acceptors.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
159.8 °F - closed cup
Flash Point(C) 
71 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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