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370622 Sigma-Aldrich

4-(Trifluoromethoxy)benzyl bromide

97%

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Properties

Related Categories Building Blocks, C8, Chemical Synthesis, Ethers, Organic Building Blocks,
Quality Level   100
assay   97%
refractive index   n20/D 1.48 (lit.)
bp   82-84 °C/10 mmHg (lit.)
density   1.594 g/mL at 25 °C (lit.)
SMILES string   FC(F)(F)Oc1ccc(CBr)cc1
InChI   1S/C8H6BrF3O/c9-5-6-1-3-7(4-2-6)13-8(10,11)12/h1-4H,5H2
InChI key   JDNPUJCKXLOHOW-UHFFFAOYSA-N

Description

General description

Polymerizations of 4-(trifluoromethoxy)benzyl bromide, via Friedel-Crafts polymerization using aluminum chloride as a catalyst has been reported.

Application

4-(Trifluoromethoxy)benzyl bromide may be used in the synthesis of bioreductive drug, (6S)-2-nitro-6-{[4-(trifluoromethoxy)benzyl]oxy}-6,7-dihydro-5H-imidazo[2,1-b][1,3]oxazine (PA-824).

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3265 8 / PGII
WGK Germany 
WGK 3
Flash Point(F) 
201.2 °F - closed cup
Flash Point(C) 
94 °C - closed cup

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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