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412708 Sigma-Aldrich

Diethyl dibromomalonate

97%

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Properties

Related Categories Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, Esters,
Quality Level   100
assay   97%
refractive index   n20/D 1.484 (lit.)
bp   140-143 °C/18 mmHg (lit.)
density   1.68 g/mL at 25 °C (lit.)
SMILES string   CCOC(=O)C(Br)(Br)C(=O)OCC
InChI   1S/C7H10Br2O4/c1-3-12-5(10)7(8,9)6(11)13-4-2/h3-4H2,1-2H3
InChI key   PFZYFZRUPFUEOB-UHFFFAOYSA-N

Description

General description

Diethyl dibromomalonate reacts with sodium methoxide in cyclohexene to afford dibromonorcarane. It also reacts with allyl(pyridine)cobaloximes to afford the corresponding allyl-substituted esters.

Packaging

25 mL in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles
Peer-Reviewed Papers
15

References

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