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412910 Sigma-Aldrich

Methyltrioxorhenium(VII)

Re 71.0-76.0 %

Synonym: MTO, Methylrhenium(VII) trioxide

  • CAS Number 70197-13-6

  • Linear Formula CH3ReO3

  • Molecular Weight 249.24

  •  Beilstein/REAXYS Number 3927932

  •  MDL number MFCD00192332

  •  PubChem Substance ID 24865831

  •  NACRES NA.22

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhenium Catalysts More...
Quality Level   100
composition   Re, 71.0-76.0%
reaction suitability   core: rhenium
  reagent type: catalyst
mp   111 °C (lit.)
SMILES string   C[Re](=O)(=O)=O
InChI   1S/CH3.3O.Re/h1H3;;;;
InChI key   PQTLALPZRPFYIT-UHFFFAOYSA-N

Description

Application

Potent catalytic oxidant for converting alkenes to epoxides in a variety of solvents and 2-methylnaphthalene to 2-methyl-1,4-naphthoquinone (Vitamin K3).
Catalytic oxidant used with urea hydrogen peroxide in an efficient conversion of imines to nitrones.
An effective antioxidant under various conditions.

Packaging

100, 500 mg in glass bottle

2 g in glass bottle

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable
Protocols & Articles
Peer-Reviewed Papers
15

References

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