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416126 Sigma-Aldrich

Trimethylolpropane diallyl ether

90%

Synonym: 2,2-Bis(allyloxymethyl)-1-butanol

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Properties

Related Categories Allyl Monomers, Materials Science, Monomers, Polymer Science
Quality Level   200
assay   90%
refractive index   n20/D 1.458 (lit.)
bp   135 °C/13 mmHg (lit.)
density   0.955 g/mL at 25 °C (lit.)
SMILES string   CCC(CO)(COCC=C)COCC=C
InChI   1S/C12H22O3/c1-4-7-14-10-12(6-3,9-13)11-15-8-5-2/h4-5,13H,1-2,6-11H2,3H3
InChI key   BDKDHWOPFRTWPP-UHFFFAOYSA-N

Description

General description

Trimethylolpropane diallyl ether (TMPAE) is an unsaturated allyl ether that can be synthesized by Williamson esterification reaction in the presence of trimethylolpropane, sodium hydroxide, and allyl chloride as starting materials.

Application

TMPAE can be used in the synthesis of isophorone diisocyanate (IPDI) based tetracene monomers which can further be used in the formation of polymer dispersed liquid crystals. It can also be used in the synthesis of allyl ether based dendrimers that find potential usage in coatings.

Packaging

1 L in glass bottle

250 mL in glass bottle

Other Notes

remainder monoethers and triethers

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
244.4 °F - closed cup
Flash Point(C) 
118 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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