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419591 Sigma-Aldrich

3-Butenylmagnesium bromide solution

0.5 M in THF

  • CAS Number 7103-09-5

  • Linear Formula H2C=CHCH2CH2MgBr

  • Molecular Weight 159.31

  •  MDL number MFCD00209554

  •  PubChem Substance ID 24866263

  •  NACRES NA.22

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Properties

Related Categories Alkyl, Aryl and Alkenyl - Grignard reagent, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
Quality Level   100
reaction suitability   reaction type: Grignard Reaction
concentration   0.5 M in THF
bp   65 °C
density   0.937 g/mL at 25 °C
SMILES string   Br[Mg]CCC=C
InChI   1S/C4H7.BrH.Mg/c1-3-4-2;;/h3H,1-2,4H2;1H;/q;;+1/p-1
InChI key   SMLLHQBZPPSOSR-UHFFFAOYSA-M

Description

Packaging

100, 800 mL in Sure/Seal™

Application

Synthetic building block that can undergo ring-formation reactions facilitated by ruthenium catalysts.

Used in a key diastereoselective step in the synthesis of (–)-muricatacin from L-tartaric acid.

Safety & Documentation

Safety Information

Signal word 
Danger
Supplemental Hazard Statements 
EUH018 - EUH019
RIDADR 
UN 3399A 4.3(3) / PGI
WGK Germany 
WGK 3
Flash Point(F) 
-22.0 °F - closed cup
Flash Point(C) 
-30 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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