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419613 Sigma-Aldrich

2-Methyl-1-propenylmagnesium bromide solution

0.5 M in THF

  • CAS Number 38614-36-7

  • Linear Formula (CH3)2C=CHMgBr

  • Molecular Weight 159.31

  •  MDL number MFCD00209600

  •  PubChem Substance ID 24866265

  •  NACRES NA.22

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Properties

Related Categories Alkenyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
Quality Level   100
reaction suitability   reaction type: Grignard Reaction
concentration   0.5 M in THF
density   0.952 g/mL at 25 °C
SMILES string   C\C(C)=C\[Mg]Br
InChI   1S/C4H7.BrH.Mg/c1-4(2)3;;/h1H,2-3H3;1H;/q;;+1/p-1
InChI key   BKVIQODYSREJQH-UHFFFAOYSA-M

Description

Packaging

100, 800 mL in Sure/Seal™

Application

Used in a study of a palladium-catalyzed coupling with aryl tosylates.

Used in a synthesis of (2S,3S)-3′-fluoroisoleucine.

Safety & Documentation

Safety Information

Signal word 
Danger
Target organs 
Respiratory system
Supplemental Hazard Statements 
EUH014 - EUH019
RIDADR 
UN 3399BC 4.3(3) / PGII
WGK Germany 
WGK 3
Flash Point(F) 
5.0 °F - closed cup
Flash Point(C) 
-15 °C - closed cup
Protocols & Articles
Peer-Reviewed Papers
15

References

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