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  • 459542 - (R)-(−)-4-Benzyl-3-propionyl-2-oxazolidinone

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459542 Sigma-Aldrich

(R)-(−)-4-Benzyl-3-propionyl-2-oxazolidinone

99%

  • CAS Number 131685-53-5

  • Empirical Formula (Hill Notation) C13H15NO3

  • Molecular Weight 233.26

  •  MDL number MFCD00269687

  •  PubChem Substance ID 24869569

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Auxiliaries, Oxazolidinone Derivatives
Quality Level   100
assay   99%
optical activity   [α]20/D −102°, c = 1 in ethanol
optical purity   ee: 99% (HPLC)
mp   44-46 °C (lit.)
SMILES string   CCC(=O)N1[C@@H](COC1=O)Cc2ccccc2
InChI   1S/C13H15NO3/c1-2-12(15)14-11(9-17-13(14)16)8-10-6-4-3-5-7-10/h3-7,11H,2,8-9H2,1H3/t11-/m1/s1
InChI key   WHOBYFHKONUTMW-LLVKDONJSA-N

Description

General description

(R)-(−)-4-Benzyl-3-propionyl-2-oxazolidinone is used as a building block in organic synthesis for the preparation of oxazolidinone derivatives.

Application

(R)-(−)-4-Benzyl-3-propionyl-2-oxazolidinone can be used as a building block for the preparation of methyl 3-[(S)-3-((R)-4-benzyl-2-oxooxazolidin-3-yl)-2-methyl-3-oxopropyl]benzoate by treating with strong base followed by the addition of methyl 3-bromomethyl benzoate.

Packaging

1, 5, 25 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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