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469424 Sigma-Aldrich

Methyl (2R)-glycidate

optical purity ee: 94% (GLC), 97%

Synonym: Methyl (R)-oxiranecarboxylate

  • CAS Number 111058-32-3

  • Empirical Formula (Hill Notation) C4H6O3

  • Molecular Weight 102.09

  •  MDL number MFCD00274191

  •  PubChem Substance ID 24870598

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks More...
Quality Level   100
assay   97%
optical activity   [α]20/D +32°, c = 1 in chloroform
optical purity   ee: 94% (GLC)
refractive index   n20/D 1.42 (lit.)
density   1.166 g/mL at 25 °C (lit.)
shipped in   wet ice
storage temp.   2-8°C
SMILES string   COC(=O)[C@H]1CO1
InChI   1S/C4H6O3/c1-6-4(5)3-2-7-3/h3H,2H2,1H3/t3-/m1/s1
InChI key   YKNYRRVISWJDSR-GSVOUGTGSA-N

Description

Packaging

5, 25 g in glass bottle

Legal Information

Manufactured under license by Sterling Pharma Solutions Limited, using Jacobsen HKR technology.

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
RIDADR 
NA 1993 / PGIII
WGK Germany 
WGK 3
Flash Point(F) 
162.0 °F - closed cup
Flash Point(C) 
72.2 °C - closed cup

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

HKR Epoxides

One of the most effective and recent methods for obtaining several classes of chiral building blocks is Jacobsen’s hydrolytic kinetic resolution technique (HKR). The method provides general access to...
Aldrich ChemFiles 2005, 5.4, 17.
Keywords: Anti-inflammatory agents, Asymmetric synthesis, Building blocks, Chemfiles, Deprotonations, Ligands, Methods

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