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469858 Aldrich

Tetrakis(dimethylamido)titanium(IV)

99.999% trace metals basis

Synonym: TDMAT, Tetrakis(dimethylamino)titanium(IV)

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Properties

Related Categories CVD and ALD Precursors by Metal, Materials Science, Micro/NanoElectronics, Titanium, Vapor Deposition Precursors More...
InChI Key   MNWRORMXBIWXCI-UHFFFAOYSA-N
Quality Level   HITECH
assay   99.999% trace metals basis
form   liquid
bp   50 °C/0.5 mmHg(lit.)
density   0.947 g/mL at 25 °C(lit.)

Description

General description

Please inquire for bulk quantity, pricing, and packaging options.

Packaging

5, 25 g in ampule

Application

Tetrakis(dimethylamido)titanium(IV) (TDMAT) is a precursor to titanium nitride (TiN) thin films by organometallic chemical vapor deposition (OMCVD)and titanium dioxide thin films by atomic layer deposition (ALD).TDMAT undergoes exothermal reaction with excess cyclopentadiene to yield tris(dimethylamido)(η5-cyclopentadienyl)titanium(IV).

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN3398 - DOT UN3399 class 4.3 - PG 1 - Organometallic substance, liquid, water-reactive, HI: all (not BR)
WGK Germany 
3
Flash Point(F) 
-22 °F
Flash Point(C) 
-30 °C

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Protocols & Articles

Articles

A Review of Mesoporous TiO2 Thin Films

Jinshu Wang*, Junshu Wu, Hongyi Li The Key Lab of Advanced Functional Materials, Ministry of Education China, School of Materials Science and Engineering, Beijing University of Technology, Beijing 10...
Keywords: Adsorption, Building blocks, Catalysis, Ceramics, Condensations, Cosmetics, Degradations, Diffraction, Eliminations, Evaporation, Materials Science, Oxidations, Polymerization reactions, Semiconductor, Separation, Sol-gel

Atomic Layer Deposition of Nanomaterials for Li-Ion Batteries, Fuel Cells, and Solar Cells

Erwin Kessels,* Harm Knoops, Matthieu Weber, Adrie Mackus, and Mariadriana Creatore Department of Applied Physics, Eindhoven University of Technology P.O. Box 513, 5600 MB Eindhoven, The Netherlands ...
Keywords: Adhesion, Atomic layer deposition, Building blocks, Catalysis, Chemical vapor deposition, Crystallization, Deposition, Diffusion, Microscopy, Nanomaterials, Nanotubes, Nucleic acid annealing, Oxidations, Recombination, Reductions, Renewable energy, Scanning electron microscopy, Solar cells

Dye-Sensitized and Perovskite Solar Cells: Interface Engineering by Atomic Layer Deposition

Valerio Zardetto,1 Francesco Di Giacomo,2 Thomas M. Brown,2 Aldo Di Carlo,2 Alessandra D’Epifanio,3 Silvia Licoccia,3 Erwin Kessels,1 Mariadriana Creatore1* 1Department of Applied Physics, Eindhoven ...
Keywords: Atomic layer deposition, Calorimetry, Capillary electrophoresis, Catalysis, Chemical vapor deposition, Deposition, Electronics, Materials Science, Microscopy, Photovoltaics, Positron Emission Tomography, Recombination, Reductions, Scanning electron microscopy, Semiconductor, Separation, Sol-gel, Solar cells

Mesoporous Titanium Dioxide Thin Films

Titanium dioxide (TiO2) is an important n-type semiconducting material that shows interesting characteristics such as photoswitchable surface wettability, high photocatalytic activity, bistable elect...
Jinshu Wang, Junshu Wu, Hongyi Li
Material Matters, Volume 7, Number 2, 2–6
Keywords: Adsorption, Building blocks, Catalysis, Ceramics, Condensations, Cosmetics, Degradations, Diffraction, Eliminations, Evaporation, Materials Science, Oxidations, Polymerization reactions, Semiconductor, Separation, Sol-gel

Nanowire Synthesis: From Top-Down to Bottom-Up

David J. Hill, James F. Cahoon* Department of Chemistry, University of North Carolina at Chapel Hill, USA *Email: jfcahoon@unc.edu
David J. Hill, James F. Cahoon*
Material Matters, 2017, 12.1
Keywords: Absorption, Catalysis, Chemical vapor deposition, Deposition, Electronics, Melting, Microelectronics, Nanomaterials, Redox Reactions, Reductions, Semiconductor

Surface-enhanced Solar Energy Conversion Systems Using Gold and Silver Nanoparticles

Sustainable, environment-friendly, and clean energy sources with sufficiently high production efficiency for practical application are highly desirable to meet the energy challenge of the 21st centur...
Shanlin Pan and Arunava Gupta
Material Matters, 2012 v7, n4
Keywords: Absorption, Applications, Catalysis, Chemical vapor deposition, Degradations, Deposition, Diffusion, Electronics, Help, Organic electronics, Photovoltaics, Recombination, Renewable energy, Search, Semiconductor, Separation, Solar cells, Spectra, Support, Type

Peer-Reviewed Papers
15

References

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