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552844 Sigma-Aldrich

3-Amino-6-bromopyridine

97%

  • CAS Number 13534-97-9

  • Empirical Formula (Hill Notation) C5H5BrN2

  • Molecular Weight 173.01

  •  MDL number MFCD01646116

  •  PubChem Substance ID 24879291

  •  NACRES NA.22

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Properties

Related Categories Building Blocks, C5, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks,
Quality Level   200
assay   97%
mp   74-76 °C (lit.)
SMILES string   Nc1ccc(Br)nc1
InChI   1S/C5H5BrN2/c6-5-2-1-4(7)3-8-5/h1-3H,7H2
InChI key   XTHKRYHULUJQHN-UHFFFAOYSA-N

Description

General description

3-Amino-6-bromopyridine can be synthesized via bromination of 3-aminopyridine using N-bromosuccinimide in acetonitrile.

Application

3-Amino-6-bromopyridine may undergo polymerization via Buchwald–Hartwig amination in the presence of sodium tert-butoxide and XPhos(2-dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl) ligand yielding para-linked and meta-linked polyaminopyridines.

Packaging

1, 5 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Precautionary statements 
Target organs 
Respiratory system
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Meet Synthia - Retrosynthesis Sofware
Protocols & Articles
Peer-Reviewed Papers
15

References

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