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661384 Aldrich

2-Iodoxybenzoic acid

contains stabilizer, 45 wt. % (IBX)

Synonym: SIBX, Stabilized IBX

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Properties

Related Categories Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Hypervalent Iodine, Oxidizing Agents,
InChI Key   CQMJEZQEVXQEJB-UHFFFAOYSA-N
contains   stabilizer
concentration   45 wt. % (IBX)

Description

Application

A stabilized formulation of IBX (SIBX) that displays none of the explosive properties of IBX, while maintaining excellent reactivity and selectivity.

Reagent used to oxidize Fmoc-protected amino alcohols to the corresponding amino aldehydes in the presence of DMSO.

Stabilized 2-Iodoxybenzoic Acid (SIBX)

Other Notes

The material is stabilized with benzoic acid and isophthalic acid

Packaging

1, 10, 50, 250 g in glass bottle

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1759 8 / PGII
WGK Germany 
3

Documents

Certificate of Analysis

Certificate of Origin


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Protocols & Articles

Articles

Passerini Reaction

The Passerini Reaction is another isonitrile-based MCR that yields a-acyloxy carboxamides in a one-pot synthesis from an aldehyde, isonitrile, and carboxylic acid. Of the three components, the carbon...
Aldrich ChemFiles 2006, 6.7, 3.
Keywords: Chemfiles, Passerini reaction

Stabilized 2-Iodoxybenzoic Acid (SIBX)

Since 1994,1 2-iodoxybenzoic acid (IBX) has been well recognized as a very powerful and selective oxidizing agent. Similar to the Dess–Martin periodinane, IBX is an environmentally benign alternative...
ChemFiles 2006, 6.2, 14.
Keywords: Dearomatizations, Oxidations

Related Content

Stabilized 2-Iodoxybenzoic Acid

From our library of Related Content, Sigma-Aldrich presents Stabilized 2-Iodoxybenzoic Acid
Keywords: Dearomatizations, Oxidations

Peer-Reviewed Papers
15

References

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