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692255 Sigma-Aldrich

RuCl2[(R)−DM−BINAP][(R)−DAIPEN]

Synonym: Dichloro[(R)−2,2′−bis[di(3,5−xylyl)phosphino]−1,1′−binaphthyl][(2R)−1,1−bis(4−methoxyphenyl)−3−methyl−1,2−butanediamine]ruthenium(II)

  • CAS Number 220114-32-9

  • Empirical Formula (Hill Notation) C71H74Cl2N2O2P2Ru

  • Molecular Weight 1221.28

  •  PubChem Substance ID 329761478

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Properties

Related Categories Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...
InChI Key   VMSNEARTLSFOHB-OEGAAENXSA-N
mp   197-211 °C
storage temp.   2-8°C

Description

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Catalyst for:
• Noyori-type enantioselective ketone hydrogenation
• Enantioselective and asymmetric hydrogenation of ketones

Packaging

100 mg in glass insert

50 mg in glass bottle

Legal Information

Sold in collaboration with Takasago for research purposes only. JP Registration No. 2041996, 2731377, 2935453 JP Application No. 19970359654

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles

Articles

Takasago Ligands and Complexes for Asymmetric Reactions

The quest to find chiral catalysts capable of achieving high enantiomeric excess for a variety of asymmetric transformations has been an ongoing endeavor for the past 40 years. One of the most releva...
Keywords: Addition reactions, Arylations, Asymmetric synthesis, Catalysis, Hydrogenations, Ligands, transformation

Related Content

Takasago Ligands - Advantages and Applications

Introduction The quest to find chiral catalysts capable of achieving high enantiomeric excess for a variety of asymmetric transformations has been an ongoing endeavor for the past 40 years. One of th...
Keywords: Addition reactions, Applications, Arylations, Asymmetric synthesis, Building blocks, Catalysis, Epoxidations, Hydrogenations, Hydrosilylations, Ligands, Sharpless Epoxidation, transformation

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