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692778 Sigma-Aldrich

(R,R)-DACH-naphthyl Trost ligand

95%

Synonym: (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphino-1-naphthoyl)

  • CAS Number 174810-09-4

  • Empirical Formula (Hill Notation) C52H44N2O2P2

  • Molecular Weight 790.87

  •  MDL number MFCD02684551

  •  PubChem Substance ID 329761526

  •  NACRES NA.22

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, Trost Ligands More...
InChI Key   VXFKMKXTPXVEMU-AWSIMMLFSA-N
assay   95%
optical activity   [α]20/D +69.0°, c = 1 in methanol
mp   224-231 °C

Description

Application

Trost Ligands for Asymmetric Allylic Alkylation

Asymmetric allylic alkylation ligand.

Packaging

1 g in glass bottle

250 mg in amber glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis (COA)

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Certificate of Origin (COO)

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Protocols & Articles

Articles

Asymmetric Allylic Alkylation - Advantages and Applications in Chemical Synthesis

. Introduction . Advantages . Representative Application . Pd-Catalyzed Asymmetric Allylic Alkylation: Carbon Nucleophiles . Pd-Catalyzed Asymmetric Allylic Alkylation: Oxygen Nucleophiles . Pd-Catal...
Keywords: Alkylations, Asymmetric synthesis, Building blocks, Catalysis, Ligands

Trost Ligands

Palladium-catalyzed asymmetric allylic alkylation (AAA) has proven to be an exceptionally powerful method for the efficient construction of stereogenic centers. In sharp contrast to many other cataly...
William Sommer and Daniel Weibel

ChemFiles 2008, 8.2, 82.
Keywords: Aldrichimica Acta, Alkylations, Asymmetric synthesis, Catalysis, Ligands, Methods

Related Content

Asymmetric Allylic Alkylation in Chemical Synthesis

Introduction Palladium-catalyzed asymmetric allylic alkylation (AAA) has proven to be an exceptionally powerful method for the efficient construction of stereogenic centers. In sharp contrast to many...
Keywords: Aldrichimica Acta, Alkylations, Asymmetric synthesis, Building blocks, Catalog, Catalysis, Ligands, Methods

Peer-Reviewed Papers
15

References

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