EMAIL THIS PAGE TO A FRIEND
693189 Sigma-Aldrich

(S)-Ru(OAc)2(BINAP)

Synonym: Diacetato[(S)-(−)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]ruthenium(II)

Purchase

Properties

Related Categories Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes More...
InChI Key   NMLZYEWNUCRSRJ-UHFFFAOYSA-L
storage temp.   2-8°C

Description

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Catalyst for:
• Synthesis of zaragozic acid D and formal syntheses of zaragozic acids A and C
• Enantioselective synthesis of the spirocyclic C-arylglycopyranoside (+)-papulacandin D via palladium-catalyzed, organosilanolate-based cross-coupling reaction and a Lewis-base catalyzed, enantioselective allylation reaction
• Asymmetric hydrogenation of 2-formyl-1-methylene-1,2,3,4-tetrahydroisoquinoline
• Asymmetric reduction of (nitro)(phenyl)propene
• Asymmetric synthesis of chiral d-lactones via hydrogenation
• Asymmetric hydrogenation of bis(diphenylphosphinoyl)butadiene

Packaging

100, 500 mg in amber glass bottle

Legal Information

Sold in collaboration with Takasago for research purposes only.

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

???PDP_SDS_LOT_NUMBER_ERROR_MSG???

Certificate of Origin

???PDP_SDS_LOT_NUMBER_ERROR_MSG???
Protocols & Articles

Articles

Takasago Ligands and Complexes for Asymmetric Reactions

The quest to find chiral catalysts capable of achieving high enantiomeric excess for a variety of asymmetric transformations has been an ongoing endeavor for the past 40 years. One of the most releva...
Keywords: Addition reactions, Arylations, Asymmetric synthesis, Catalysis, Hydrogenations, Ligands, transformation

Related Content

Takasago Ligands - Advantages and Applications

Introduction The quest to find chiral catalysts capable of achieving high enantiomeric excess for a variety of asymmetric transformations has been an ongoing endeavor for the past 40 years. One of th...
Keywords: Addition reactions, Applications, Arylations, Asymmetric synthesis, Building blocks, Catalysis, Epoxidations, Hydrogenations, Hydrosilylations, Ligands, Sharpless Epoxidation, transformation

Related Products

Technical Service:

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Bulk Ordering & Pricing:

Need larger quantities for your development, manufacturing or research applications?