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702943 Sigma-Aldrich

Cy-vBRIDP

Synonym: 2-(Dicyclohexylphosphino)-1,1-diphenyl-1-propene, Dicyclohexyl(1-methyl-2,2-diphenylvinyl)phosphine

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
InChI Key   YMSBPYCREGBACF-UHFFFAOYSA-N
mp   124-130 °C
storage temp.   2-8°C

Description

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Catalyst for cycloaddition reactions

Packaging

100, 500 mg in glass bottle

Legal Information

Sold in collaboration with Takasago for research purposes only. US6455720

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

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Protocols & Articles

Articles

Amination of Aryl Halides

The Buchwald-Hartwig amination reaction, or the coupling between an aryl halide and an amine, is extremely important in various areas of both academic and industrial research. The amination of aryl c...
Josephine Nakhla
Aldrich ChemFiles 2009, 9.2, 11.
Keywords: Aminations, Buchwald-Hartwig amination, Catalysis, Chemfiles, Ligands

BRIDP Catalysts

Researchers at Takasago developed two phosphine-based ligands for the Buchwald-Hartwig amination reaction with successful results for the cross-coupling of a wide array of amines and aryl halides. Th...
Josephine Nakhla
Aldrich ChemFiles 2009, 9.2, 11.
Keywords: Aminations, Arylations, Buchwald-Hartwig amination, Catalysis, Chemfiles, Cross couplings, Electronics, Ligands

Ferrocenyl Based Ligands and Catalysts

Hartwig and co-workers have reported the use of the electron-rich and bulky ligand 1,1’-bis(di-tert-butylphosphino)ferrocene for the amination of aryl halides and for the first amination of aryl tosy...
Josephine Nakhla
Aldrich ChemFiles 2009, 9.2, 11.
Keywords: Aminations, Catalysis, Chemfiles, Eliminations, Ligands, Oxidative additions, Reductive eliminations

Takasago Ligands and Complexes for Asymmetric Reactions

The quest to find chiral catalysts capable of achieving high enantiomeric excess for a variety of asymmetric transformations has been an ongoing endeavor for the past 40 years. One of the most releva...
Keywords: Addition reactions, Arylations, Asymmetric synthesis, Catalysis, Hydrogenations, Ligands, transformation

Related Content

BRIDP from Takasago - New Ligands for Cross-Coupling Catalysts

Cross-couplings have been an essential reaction class for the past 20 years. They are used for the synthesis of a plethora of products ranging from drug molecules to polymers. Since the first report ...
Keywords: Aminations, Buchwald-Hartwig amination, Catalysis, Coupling reactions, Cross couplings, Ligands, Pharmaceutical

Takasago Ligands - Advantages and Applications

Introduction The quest to find chiral catalysts capable of achieving high enantiomeric excess for a variety of asymmetric transformations has been an ongoing endeavor for the past 40 years. One of th...
Keywords: Addition reactions, Applications, Arylations, Asymmetric synthesis, Building blocks, Catalysis, Epoxidations, Hydrogenations, Hydrosilylations, Ligands, Sharpless Epoxidation, transformation

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