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715298 Sigma-Aldrich

1,2,4,5-Tetrakis(4-carboxyphenyl)benzene

Green Alternative

contains up to 6 wt. % water, ≥98%

Synonym: 4,4′,4′′,4′′′-benzene-1,2,4,5-tetrayltetrabenzoic acid, H4TCPB

  • Empirical Formula (Hill Notation) C34H22O8

  • Molecular Weight 558.53

  •  MDL number MFCD16621436

  •  PubChem Substance ID 329762960

  •  NACRES NA.23

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Properties

Related Categories Alternative Energy, Chemical Synthesis, Enabling Products, Greener Alternative Products, Material Science Enabling Products,
Quality Level   100
assay   ≥98%
greener alternative product characteristics   Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
SMILES string   OC(=O)c1ccc(cc1)-c2cc(-c3ccc(cc3)C(O)=O)c(cc2-c4ccc(cc4)C(O)=O)-c5ccc(cc5)C(O)=O
InChI   1S/C34H22O8/c35-31(36)23-9-1-19(2-10-23)27-17-29(21-5-13-25(14-6-21)33(39)40)30(22-7-15-26(16-8-22)34(41)42)18-28(27)20-3-11-24(12-4-20)32(37)38/h1-18H,(H,35,36)(H,37,38)(H,39,40)(H,41,42)
InChI key   SRTQKANXPMBQCX-UHFFFAOYSA-N

Description

General description

1,2,4,5-Tetrakis(4-carboxyphenyl)benzene (H4TCPB) is an organic linker with a molecular structure that has four carboxyl phenyl groups that are symmetrically attached to the central benzene core. It can be synthesized by using a Suzuki coupling reaction.

Sigma Life Science is committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

(H4TCPB) can be used for a variety of applications such as:
• the formation of supramolecular heterostructures to functionalize black phosphorus
• synthesis of microporous metal-organic frameworks (MOFs) for potential usage in hydrogen storage, gas separation, and catalysis.

Selected Applications of MOFs in Sustainable Energy Technologies

[1,1′:4′,1]Terphenyl- 3,3″,5,5″-tetracarboxylic acid (H4TPTC) is used as a linker molecule for the synthesis of high performance metal-organic frameworks (MOFs).

Packaging

1 g in glass bottle

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
185.0 °F - closed cup
Flash Point(C) 
85 °C - closed cup

Documents

Certificate of Analysis (COA)

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Protocols & Articles

Articles

DO-MOF | Metal-Organic Frameworks (MOF's)

Explore MOF Applications, Properties and Materials to construct MOFs in the MOF Constructor Tool
Keywords: Adsorption, Metal organic frameworks

DTO - MOF | Metal-Organic Frameworks (MOF's)

Explore MOF Applications, Properties and Materials to construct MOFs in the MOF Constructor Tool
Keywords: Adsorption, Metal organic frameworks

MnSO - MOF | Metal-Organic Frameworks (MOF's)

Explore MOF Applications, Properties and Materials to construct MOFs in the MOF Constructor Tool
Keywords: Applications, Catalysis, Epoxidations, Metal organic frameworks

Selected Applications of Metal-Organic Frameworks in Sustainable Energy Technologies

Although the field of high surface area materials is considered very mature, the need for improved materials for alternative energy applications remains pressing. Currently, zeolites, metal oxides, a...
Stephen R. Caskey, Adam J. Matzger
Material Matters 2009, 4.4, 111.
Keywords: Adsorption, Alternative energy, Combustion, Diffraction, Environmental, Filtration, Infrared spectroscopy, Ligands, Metal organic frameworks, Purification, Scintillation, Separation, Solvents, Sonication, X-Ray diffraction

TO - MOF | Metal-Organic Frameworks (MOF's)

Explore MOF Applications, Properties and Materials to construct MOFs in the MOF Constructor Tool
Keywords: Adsorption, Metal organic frameworks

YO - MOF | Metal-Organic Frameworks (MOF's)

Explore MOF Applications, Properties and Materials to construct MOFs in the MOF Constructor Tool
Keywords: Adsorption, Metal organic frameworks

ZnPO - MOF | Metal-Organic Frameworks (MOF's)

Explore MOF Applications, Properties and Materials to construct MOFs in the MOF Constructor Tool
Keywords: Catalysis, Metal organic frameworks

Related Content

MOF Constructor

Metal-Organic Frameworks (MOFs) are a novel class of 3D networked, crystalline materials composed of metal ions or clusters connected by organic linkers. Given their porous nature and often high surf...

Peer-Reviewed Papers
15

References

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