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731110 Sigma-Aldrich

Di-n-butylmagnesium solution

Green Alternative

1 M in ether and hexanes

  • CAS Number 1191-47-5

  • Linear Formula [CH3(CH2)3]2Mg

  • Molecular Weight 138.53

  •  Beilstein/REAXYS Number 3535184

  •  MDL number MFCD00015225

  •  PubChem Substance ID 329764622

  •  NACRES NA.23

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Properties

Related Categories Alternative Energy, Chemical Synthesis, Enabling Products, Greener Alternative Products, Material Science Enabling Products,
Quality Level   100
greener alternative product characteristics   Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
concentration   1 M in ether and hexanes
density   0.736 g/mL at 25 °C
SMILES string   CCCC[Mg]CCCC
InChI   1S/2C4H9.Mg/c2*1-3-4-2;/h2*1,3-4H2,2H3;
InChI key   ODHFJIDDBSDWNU-UHFFFAOYSA-N

Description

General description

Di-n-butylmagnesium solution may be prepared by hydrogenation of magnesium, followed by reacting it with 1-butene.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Electrochemically inactive [Mg2(μ-Cl)3•6THF][C2H5AlCl3] crystal may be obtained from an electrolyte composed of Di-n-butylmagnesium and ethylaluminum dichloride. Di-n-butylmagnesium may be used in the carbon metallation of α-olefins. A study reports the possible use of the organometallic compound in the intercalation of magnesium and zinc into the layers of TiS2 or WO2Cl2. Interaction of lithium alkoxide with di-n-butylmagnesium was investigated.

Packaging

100 mL in Sure/Seal™

Safety & Documentation

Safety Information

Signal word 
Danger
Target organs 
Central nervous system
Supplemental Hazard Statements 
EUH014 - EUH019
RIDADR 
UN 3399A 4.3(3) / PGI
WGK Germany 
WGK 2
Flash Point(F) 
-22.0 °F
Flash Point(C) 
-30 °C

Documents

Certificate of Analysis (COA)

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Protocols & Articles
Peer-Reviewed Papers
15

References

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