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749125 Sigma-Aldrich

Cobalt(II) oxo pivalate

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Synonym: Basic cobalt(II) pivalate, Cobalt, hexakis[μ-(2,2-dimethylpropanoato-κO:κO′)]hexakis[μ3-(2,2-dimethylpropanoato-κO:κO:κO′)]di-μ4-oxoocta-, Tetrameric Co cluster

  • CAS Number 301663-94-5

  • Empirical Formula (Hill Notation) C60H108Co8O26

  • Molecular Weight 1716.95

  •  MDL number MFCD22200509

  •  PubChem Substance ID 329765968

  •  NACRES NA.23

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Properties

Related Categories Alternative Energy, Chemical Synthesis, Enabling Products, Greener Alternative Products, Material Science Enabling Products,
Quality Level   100
form   powder
greener alternative product characteristics   Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
SMILES string   CC(C)(C)C(=O)O[Co-]1O[Co-](O\C(=[O+]/[Co-](OC(=O)C(C)(C)C)O\C(=[O+]/[Co-](OC(=O)C(C)(C)C)OC(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C)[O+]=C(O[Co-]2O[Co-](O\C(=[O+]\1)C(C)(C)C)\[O+]=C(\O[Co-](OC(=O)C(C)(C)C)\[O+]=C(\O[Co]OC(=[O+]2)C(C)(C)C)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI   1S/12C5H10O2.8Co.2O/c12*1-5(2,3)4(6)7;;;;;;;;;;/h12*1-3H3,(H,6,7);;;;;;;;;;/q;;;;;;;;;;;;4*+1;4*+2;;/p-12
InChI key   PBKALLJUIAKYSI-UHFFFAOYSA-B

Description

General description

Cobalt(II) oxo pivalate is a dinuclear complex that is typically formed by the direct reaction of cobalt carbonate with pivalic acid, followed by crystallization from MeCN. Its structure has two Co(II) sites bridged by two 2,11-carboxylates (Harris notation) and an oxygen atom.

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Application

Synthesis of trinuclear complex [Co3(Piv)2L12L22] by reacting cobalt(II)pivalate with spin labeled Schiff base has been reported in a study.

Packaging

500 mg in glass insert

Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
WGK 3
Flash Point(F) 
Not applicable
Flash Point(C) 
Not applicable

Documents

Certificate of Analysis (COA)

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Protocols & Articles

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References

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